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Chlorinated Solvents in Fractured-Rock Aquifers—Naval Air Warfare Center (NAWC) Research Site, West Trenton, New Jersey

USGS scientists processing cores for later laboratroy analysis.
USGS scientists processed cores for later analysis of trichloroethylene (TCE), dichloroethylene (DCE), and vinyl chloride in the cores (circa 2005). A blue tarp was laid on the ground to capture any spills of potentially contaminated materials from the cores.

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Toxic chemicals such as chlorinated solvents in fractured rock aquifers pose a serious threat to the Nation's ground-water resources. Many industrial centers in America are located in the piedmont physiographic region where fractured rock aquifers are common. Improper disposal methods, leaking tanks and pipes, and chemical spills have contaminated fractured rock aquifers in and around many industrial centers. The restoration and protection of ground-water quality depend on knowledge of the physical, chemical, and microbiological processes that affect the fate of these toxic chemicals in fractured rock aquifers. The intent of this investigation is to help develop the knowledge needed to create practical and cost-effective methods to clean up and protect ground-water resources in fractured rock aquifers.

The NAWC Research Site, West Trenton, New Jersey, is located 4 miles north of Trenton, NJ. The fractured bedrock at the site has been contaminated with trichloroethylene (TCE)--a chlorinated solvent. The plume of TCE was caused by leakage of TCE from aboveground service lines and storage tanks. The TCE was used as a heat transfer agent during jet engine tests. An estimated 100,000 gallons of TCE was lost through leakage and spills at the site. Dense nonaqueous phase liquids (DNAPL) have been identified at the site, and have flowed vertically downward and in the down-dip direction of the fractured sedimentary rocks. The aqueous phase plume of dissolved TCE has flowed along the strike and the up-dip directions of the sedimentary rocks. There is evidence of natural attenuation of TCE, probably and at least in part due to the presence of a jet-fuel oil spill that overlaps part of the plume.

Detail of TCE pipes that were cut during remedial activities at the NAWC Site
Detail of TCE pipes that were cut during remedial activities at the NAWC Site. Through leakage and spills an estimated 100,000 gallons of TCE was lost.

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  • Stable carbon isotope fractionation during bacterial acetylene fermentation : Miller, L.G., Baesman, S.M., and Oremland, R.S., Astrobiology (IN PRESS).

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