Environmental Health - Toxic Substances Hydrology Program
U.S. Geological Survey (USGS) scientists use electrical geophysical tests to monitor how rate-limited mass transfer (see text box) controls the movement of contaminants between the host rock (rock matrix) and the more permeable fractures in fractured rock aquifers. The method involves injecting water with an electrical conductivity different from the groundwater (a different salinity, for example) into a well and then pumping it back out of the ground from the same well. The scientists monitor this “push-pull” tracer test by sending electrical current into the ground with two electrodes in a nearby well; the resulting difference in voltage is measured by two neighboring receiving electrodes in the same well. This procedure was repeated for many different combinations of electrodes. The information from the combined geophysics/hydraulic tracer test is used to calculate rate-limited mass transfer coefficients that are based on the realistic field-scale data provided by the push-pull tracer test. The scientists use the coefficients to more accurately simulate the transport of contaminants in fractured rock.
Culkin, S.L., Singha, K., and Day-Lewis, F.D., 2008, Implications of rate-limited mass transfer for aquifer storage recovery efficiency: Groundwater, v. 46, no. 4, pp. 591-605, doi:10.1111/j.1745-6584.2008.00435.x.
Day-Lewis, F.D., and Singha, K., 2008, Geoelectrical inference of mass transfer parameters using temporal moments: Water Resources Research, v. 44, W05201, doi:10.1029/2007WR006750.
Singha, K., F. D. Day-Lewis, and Lane, J.W., 2007, Geoelectrical evidence of bicontinuum transport in groundwater: Geophysical Research Letters, v. 34, no. 12, L12401, doi:10.1029/2007GL030019.
Singha, K., Pidlisecky, A., Day-Lewis, F.D., and Gooseff, M.N., 2008, Electrical characterization of non-Fickian transport in groundwater and hyporheic systems: Water Resources Research, v. 44, W00D07, doi:10.1029/2008WR007048.